Mike,
You knew I would be here with some drivel.
For brass models you will need a hotter gun than for wiring. I have a dual range 100W/200W gun that works for both wiring and brass. Also be sure you have a supply of "heat sinks" to put on either side of your intended joint. Wouldn't want the other joints to melt again would we. I use alligator clips in various sizes. Watch out! They really get hot!
Use the same rosin-core solder you do for your wiring so you will not have to apply a separate flux. Be sure your gun tip is clean and "tinned". Now step by step.
1. Make sure the work is clean using a file, or wire brush to expose bright metal surfaces. Also be sure the parts mesh well and you have a good mechanical or physical connection.
2. Be sure to apply your heat sinks and secure the joint to be made so it will not move by vise, clamps or pins.
3. Hold the hot soldering gun to the joint so it touches both pieces to be joined.
4. Touch the solder to the joint work and NOT to the tip of the gun. When the work is hot enough to melt the solder it is at the right temperature for the chemical bond. Allow a small amount of solder to flow into the joint.
5. When the joint is wet with the solder, remove the solder, then the gun, being careful not to disturb the joint.
6. Keep the joint still until the solder cools with a bright, shiny surface. If the work moves before the solder cools, it will make a cold joint, one with a dull or frosted surface which will not be a reliable connection.
7. If you have applied too much solder, you may file off the excess gently.
This is basically the same for brass parts and wire connections.
Pete