They usually buy a high priced item using an echeck to pay. When they use an echeck, the money in Pay Pal shows pending. A seller sees that they made a sale and not checking their Pay Pal account to make sure the payment cleared and it's ok to ship, they go ahead and ship the product. A day or so later, when the echeck doesn't clear is where the problem is, but by this time the package is on it's way to the crook.
Always log into your Pay Pal account and make sure the payment has been completed before shipping.
Have a great day